91-66-7 (N,N-Diethylaniline): Safety, Handling, and Storage Guidelines

Introduction

91-66-7 (N,N-Diethylaniline) is a widely used aromatic tertiary amine in the chemical industry. It plays an important role in dye manufacturing, rubber chemicals, pharmaceuticals, and specialty organic synthesis. Due to its chemical nature and potential health hazards, proper safety, handling, and storage practices are essential when working with this compound.

This article provides a comprehensive guide to the safe use, risk management, and storage requirements of 91-66-7 (N,N-Diethylaniline) in laboratory and industrial environments.


Chemical Identity and Basic Information

  • Chemical Name: N,N-Diethylaniline

  • CAS Number: 91-66-7

  • Molecular Formula: C₁₀H₁₅N

  • Molecular Weight: 149.23 g/mol

  • Chemical Class: Aromatic tertiary amine

  • Appearance: Colorless to pale yellow liquid

  • Odor: Characteristic amine-like odor

N,N-Diethylaniline consists of an aniline ring substituted with two ethyl groups attached to the nitrogen atom, giving it enhanced basicity and reactivity compared to aniline.


Hazard Overview

Like many aromatic amines, N,N-Diethylaniline may pose health and environmental risks if improperly handled.

Potential Health Hazards

  • Skin and eye irritation

  • Respiratory tract irritation

  • Harmful if inhaled or absorbed through skin

  • Possible toxic effects with prolonged exposure

  • May cause methemoglobinemia in high exposure cases

Environmental Hazards

  • Toxic to aquatic life

  • Should not be released into drains or natural water systems

Proper risk assessment should be conducted before handling this compound in bulk quantities.


Safe Handling Guidelines

1. Personal Protective Equipment (PPE)

When handling 91-66-7 (N,N-Diethylaniline), always use:

  • Chemical-resistant gloves (nitrile or neoprene)

  • Safety goggles or face shield

  • Laboratory coat or chemical-resistant apron

  • Respiratory protection if ventilation is insufficient

2. Ventilation Requirements

  • Use in well-ventilated areas

  • Preferably handle inside a fume hood

  • Avoid inhalation of vapors

3. Safe Work Practices

  • Avoid direct skin contact

  • Do not ingest or inhale vapors

  • Wash hands thoroughly after handling

  • Do not eat, drink, or smoke in work areas


First Aid Measures

In case of accidental exposure:

  • Skin Contact: Wash immediately with soap and water

  • Eye Contact: Rinse thoroughly with water for at least 15 minutes

  • Inhalation: Move the affected person to fresh air

  • Ingestion: Seek immediate medical attention

Always provide the Safety Data Sheet (SDS) to medical personnel.


Storage Guidelines

Proper storage of 91-66-7 (N,N-Diethylaniline) ensures stability and reduces risk.

Recommended Storage Conditions

  • Store in tightly sealed containers

  • Keep in a cool, dry, well-ventilated area

  • Protect from direct sunlight

  • Keep away from heat and ignition sources

  • Store away from strong oxidizing agents and acids

Container Requirements

  • Use corrosion-resistant containers

  • Ensure proper labeling with hazard warnings

  • Maintain secondary containment in industrial settings


Spill and Emergency Procedures

Small Spills

  • Absorb with inert material (sand, vermiculite)

  • Collect in chemical waste container

  • Dispose according to local regulations

Large Spills

  • Evacuate area

  • Use appropriate protective equipment

  • Prevent environmental contamination

  • Contact emergency response team


Disposal Considerations

  • Dispose of in accordance with local, regional, and national regulations

  • Do not discharge into wastewater systems

  • Follow hazardous waste management guidelines

Industrial facilities should follow environmental compliance standards to avoid regulatory violations.


Regulatory and Compliance Notes

N,N-Diethylaniline is subject to chemical safety regulations in many countries. Businesses must ensure:

  • Proper labeling and documentation

  • Compliance with occupational safety guidelines

  • Maintenance of updated Safety Data Sheets

  • Employee training programs


Conclusion

91-66-7 (N,N-Diethylaniline) is an important industrial chemical with wide-ranging applications, but it requires careful handling due to its potential health and environmental risks. By following strict safety procedures, using appropriate PPE, and adhering to recommended storage practices, industries can minimize hazards and ensure safe operations.

Implementing proper chemical safety management not only protects workers but also ensures regulatory compliance and environmental responsibility.